tpee锛氱啽濉戞€ц仛閰綀鎬ч珨绨＄ūTPEE鎴�COPE锛屾槸涓€椤炲惈鏈�PBT(鑱氬皪鑻簩鐢查吀涓佷簩閱囬叝)鑱氶叝纭(绲�(ji茅)鏅剁浉)鍜岃剛鑲棌鑱氶叝鎴栬仛閱�(闈炴櫠鐩�)杌熸鐨勭窔鍨嬪祵娈靛叡鑱氱墿銆�TPEE灞簬楂樻€ц兘宸ョ▼绱氬綀鎬ч珨锛屽叿鏈夋姊板挤搴﹂珮銆佸綀鎬уソ銆佹姉娌栨搳銆佽€愯爼璁�銆佽€愬瘨銆佽€愬綆鏇茬柌鍕炴€с€佽€愭补銆佽€愬寲瀛�(xu茅)钘ュ搧鍜屾憾鍔戜镜铦曠瓑鍎�(y艒u)榛�锛屽叿鏈夎壇濂界殑鍔犲伐鎬э紝骞跺彲濉厖銆佸寮峰強鍚堥噾鍖栨敼鎬�锛屽湪姹借粖闆堕儴浠�銆佹恫澹撹粺绠�銆侀浕绾滈浕绶�銆侀浕瀛愰浕鍣�銆佸伐妤�(y猫)鍒跺搧銆佹枃楂旂敤鍝併€佺敓鐗╂潗鏂欑瓑闋�(l菒ng)鍩熷緱鍒颁簡寤ｆ硾鐨勬噳(y墨ng)鐢�銆�
渚涙噳(y墨ng):绌�(w臎n)瀹氫緵鎳�(y墨ng)keyflex鑰愰珮婧�
鐐轰簡鑰冨療鑷埗鑶﹂吀閰樆鐕冨姂(DP-FR)灏嶇啽濉戞€ц仛閰綀鎬ч珨(TPEE)鐔辨€ц兘鐨勫奖闊�, 娓緱浜嗛樆鐕�TPEE(FRTPEE)鍏辨贩鏉愭枡绌烘埃姘ｆ皼涓嬮潪绛夋韩?z茅)宥�?/span>(TG)鏁�(sh霉)鎿�(j霉), 鍒╃敤Kissinger 鍜�Flynn-Wall-Ozawa 鍏╃ó鍕曞姏瀛�(xu茅)鏂规硶, 鍒嗗垾姹傚緱浜�FR-TPEE 鐔辨哀闄嶈В鍙嶆噳(y墨ng)娲诲寲鑳�Ea .绲�(ji茅)鏋滆〃鏄�:DP-FR灏�FR-TPEE 鐨勫垵濮嬪垎瑙ｆ韩搴︺€侀檷瑙ｆ韩搴﹀奖闊夸笉澶�, 灏嶅弽鎳�(y墨ng)娲诲寲鑳界◢鏈夊奖闊�, 闃荤噧鏉愭枡浠嶅叿鏈夊緢楂樼殑鐔辩┅(w臎n)瀹氭€�.鐮旂┒绲�(ji茅)鏋滈倓琛ㄦ槑:DP-FR 鎻愰珮浜�FR-TPEE 鐔辨哀闄嶈В鐨勮唱(zh矛)閲忎繚鐣欑巼, 椤ず鍑鸿純濂界殑闃荤噧鎬�.闂�(gu膩n)閸佃:鐔卞鎬ц仛閰綀鎬ч珨(TPEE);闃荤噧鍔�;鍕曞姏瀛�(xu茅);鐔辨哀闄嶈В;鍙嶆噳(y墨ng)娲诲寲鑳�
Abstract :T he effect s of pho spho nate ester f lame re tardant (DP-FR)o n the rmal stability of f lame re tardant thermo plastic polyester elastomer (FR-TPEE)blends were studied .The kine tics o f the thermal o xidat ive degradation o f FR-TPEE blends w ere invest igated by non-iso thermal thermog ravime tric analy sis in air .Kissinger b and Fly nn-Wall-Ozawa b had been used to dete rmine the activat ion energies o f FRTPEE deg radatio n , respectively .The resul ts show ed that DP-FR had a li t tle inf luence on init ial deg radation temperature , maximum deg radation temperature and activ ation energies , but the FR-TPEE blends still had g ood thermal stabili ty .The result s also show ed that FR-TPEE blends had high char yield ,and also demo nst rated the good f lame retardancy of DP-FR .
Key words:thermo plastic po lyester elastomer (TPEE);f lame retardant (FR);kine tics ;thermal o xidat ive deg radation ;activation energy
渚涙噳(y墨ng):绌�(w臎n)瀹氫緵鎳�(y墨ng)keyflex鑰愰珮婧�
鐔卞鎬ц仛閰綀鎬ч珨(TPEE)锛屽畠鐨勪富瑕佹垚鍒嗘槸鑱氬皪鑻簩鐢查吀浜岄唶鑴�(PBrI1)鐐虹‖娈�(绲�(ji茅)鏅剁浉)锛岃仛閱氭垨鑱氶叝鐐鸿粺娈电殑宓屾鍏辫仛鐗�(闈炴櫠鐩�)銆傛瘮杓冪‖娈靛拰杌熸锛岄€茶鍒ゆ柗浠栧€戜箣闁撶殑纭害鍙婄墿鐞嗙殑姗熸鎬ц兘銆傜‖娈甸€愭几褰㈡垚鐗╃悊鐨勯€ｆ帴榛�锛屽叾鑷韩鎵垮彈澶栫晫鍜屽収(n猫i)閮ㄧ殑鎳�(y墨ng)鍔�锛涜粺娈垫槸鍧囧嫽鍒嗘暎鐨勯珮褰堟€ч張娈�銆傜暥(d膩ng)婧害浣庝簬TPEE鐔旈粸鏅傦紝纭鐧�(f膩)閮ㄥ垎绲�(ji茅)鏅�锛屽舰鎴愮殑閫ｆ帴榛炶捣鍒扮墿鐞嗕氦鑱�(li谩n)榛炵殑浣滅敤锛屼繚璀�TPEE鍒跺搧涓嶆渻璁婂舰锛涜€岃粺娈电殑鐜荤拑鍖栨韩搴﹀緢浣�锛屽拰閮ㄥ垎鏈祼(ji茅)鏅剁殑纭褰㈡垚閫ｇ簩(x霉)鐩�銆傝粺娈电殑鐜荤拑鍖栨韩搴﹁垏纭鐨勭祼(ji茅)鏅舵韩搴︿箣闁撶殑鑼冨湇寰堝锛屽湪閫欏€嬫韩搴﹀崁(q奴)闁撳収(n猫i)锛屾潗鏂欑殑濉戞€х敘(ch菐n)鐢燂紝鍙互閲囩敤姣旇純绨″柈鐨勫伐钘濋€茶鍔犲伐銆備笉閬庨€欑ó鐗╃悊浜よ伅(li谩n)鐨勬€ц唱(zh矛)涓嶆槸寰堢┅(w臎n)瀹氾紝鏄撳彈婧害鐨勫奖闊�锛屾韩搴︾殑闄嶄綆纭鐨勬潫绺涘姏灏辨渻涓婂崌锛屽嚭鐝�(xi脿n)纭寲姗¤啝鐨勭壒榛�銆�缍滃悎鐨勫姏瀛�(xu茅)鎬ц兘杓冮珮
TPEE鏈夐潪甯稿ぇ鐨勭‖搴﹁寖鍦嶏紝鍦ㄨ(di脿o)绡€(ji茅)杌熺‖娈垫瘮渚嬪悗锛�TPEE鐨勭‖搴﹀彲浠ュ緸閭垫皬30锝�82D锛屽畠鐨勫綀鎬ц浣庝簬姗¤啝锛岄珮浜庡鏂欍€傚悓鍏朵粬鐔卞鎬у綀鎬ч珨(TPE)鐩告瘮杓�锛屽湪浣庢噳(y墨ng)璁婄殑鏅傚€�锛屽叾浠栫殑鐔卞鎬у綀鎬ч珨瑕佹瘮鐩稿悓纭害鐨�TPEE妯￠噺瑕佷綆銆傝嫢浠ユā閲忕偤閲嶈鐨勮ō(sh猫)瑷堟浠�锛屽埗鍝佺殑姗埅闈㈢⿳鍙互鐢�TPEE鍒朵綔寰楄純灏忥紝瀵﹂鐨勬ǎ鍝佸鍘氫篃鍙互鏇磋杽涓€浜�锛岄€欐ǎ灏卞彲浠ュ緢澶х▼鐨勬笡灏戞潗鏂欑殑鐢ㄩ噺銆�TPEE鏈夎憲闈炲父濂界殑鎷変几寮峰害锛岄煂鎬у拰鍥炲綀鎬ч兘鏄サ鐐虹殑銆�TPEE鎷変几妯￠噺鍜屽绺ā閲忚閬犻仩楂樹簬鑱氭皑鑴�(11PU)锛�TPEE鍜岋紟rPu鍦ㄩ€茶鍒朵綔鐩稿悓鍒跺搧鏅�锛屼竴鑸儏娉佷笅TPEE鐨勫綆鏇叉ā閲忓緢楂�锛岃€屽湪婧害杓冧綆鐨勬檪鍊� rPu鐨勭‖搴﹂亷楂�锛屽熀浜庝互涓婄殑鎬ц兘姣旇純锛�TPEE浣滅偤鎵煩鍨嬮儴浠跺拰鎳歌噦姊侀潪甯稿悎閬╋紝灏ゅ叾鏄湪楂樻韩閮ㄤ欢鐨勫埗浣滀笂锛屾洿鍏锋湁鍎�(y艒u)鍕�銆�TPEE鐨勬煍闋嗘€у湪浣庢韩鏅傞珨鐝�(xi脿n)鐨勬洿濂�锛屽叾娌栨搳寮峰害瑕侀仩鍕濅簬鍏朵粬TPE锛屽叿鏈�TPU鐩哥暥(d膩ng)?sh霉)鍝箥銈虹敺?/span>[1銆�TPEE閭勬湁钁楅潪甯稿ソ鐨勮€愮柌鍕炴€ц兘锛屽挨鍏舵槸鍦ㄤ綆鎳�(y墨ng)璁婃浠朵笅锛屽洜鐐烘化鐩炬悕澶卞皯锛屽湪鑸囧拰楂樺綀鎬ч€茶绲�(ji茅)鍚堝悗锛屽畠鏇村姞閬╁悎鍦ㄥ娆″惊鐠�(hu谩n)璨犺級鐨勬浠朵笅浣跨敤锛屾墍浠ュ湪榻掕吉銆佺毊甯�銆佽啝杓ョ殑鍒跺搧涓緱鍒板唬娉涚殑鎳�(y墨ng)鐢�銆�
渚涙噳(y墨ng):绌�(w臎n)瀹氫緵鎳�(y墨ng)keyflex鑰愰珮婧�
S锛歂鐨勭ó椤�銆佸垎瀛愰噺灏嶏細S锛氭€ц兘鐨勫奖闊匡細鎻愰珮鎽绘贩鐨凷锛歂鐨勫垎瀛愰噺锛岋細S锛氭ü鑴傜殑娌栨搳寮峰害鎻愰珮锛屾祦鍕曟€т笅闄�锛涢伕鐢ㄤ笝鐑厛鍚噺楂樼殑S锛歂鎽绘贩锛屾ü鑴傜殑鎷変几寮峰害銆佹矕鎿婂挤搴�銆佺啍楂斿挤搴﹀緱浠ユ彁楂�锛屾祦鍕曟€т笅闄�锛岃€愬寲瀛�(xu茅)鍝佹€ф彁楂�銆傛敼璁婅垏鎺ユ灊鐨勶細S锛氱矇鎽绘贩鐨凷锛歂鐨勭ó椤炪€佺墝铏燂紝鍙互鐢熺敘(ch菐n)鍏锋湁涓嶅悓鐗╂€х殑鐢�(ch菐n)鍝�锛屼娇鐗岃櫉澶氭ǎ鍖栥€傛鑶犲惈閲忓皪锛歋锛氭€ц兘鐨勫奖闊夸竴鑸渚�锛屾懟娣风殑S锛歂鍝佺ó鍥哄畾鏅�锛屾彁楂樻鑶犲惈閲�锛屾媺浼稿挤搴�銆佸綆鏇插挤搴�銆佺啽璁婂舰婧害銆丮I涓嬮檷锛岃€屾矕鎿婂挤搴�銆佹媺浼告柗瑁備几闀风巼鎻愰珮銆�
