鏉辫帪甯傚唬妤�(y猫)濉戣啝鍘熸枡鏈夐檺鍏徃閵峰敭pc/abs fr2010,浠ヤ笅鏄痯c/abs fr2010? 鐩搁棞(gu膩n)浠嬬垂锛屾杩庝締闆绘唇璜囧悎浣滐紝鍜ㄨ鐔辩窔锛�13412886878閯х敓锛�
涓€銆�pc/abs fr2010浣庡厜婢ゅ害PC/ABS鍚堥噾鐨勫奖闊垮洜绱犵爺绌讹細
PC/ABS鍚堥噾缍滃悎浜嗚仛纰抽吀閰�(PC)鍜屼笝鐑厛-涓佷簩鐑�-鑻箼鐑笁鍏冨叡鑱氱墿(ABS)鐨勫劒(y艒u)榛�锛屽挤搴﹂珮銆侀煂鎬уソ銆佽€愮啽鎬ч珮銆佸姞宸ユ€ц兘鍎�(y艒u)鑹�锛屽湪姹借粖闋�(l菒ng)鍩熷緱鍒颁簡寤f硾鎳�(y墨ng)鐢�銆備絾鏄櫘閫�PC/ABS鍚堥噾鍏夋兢搴﹁純楂�锛岀洿鎺ョ敤浜庢苯杌婂収(n猫i)椋炬槗鍙嶅厜锛屾渻閫犳垚椐曢鍝¤瑕虹柌鍕炪€傚洜姝ゆ苯杌婂収(n猫i)椋炬潗鏂欏皪鍏夋兢搴︽湁涓€瀹氱殑瑕佹眰锛岄€氬父瑕佹眰鑵扮窔浠ヤ笂鍗€(q奴)鍩熺殑鍏�(n猫i)椋炬潗鏂欑毊绱嬮潰鍏夋兢搴︿綆浜�2锛屽厜闈㈠厜婢ゅ害鍦�3宸﹀彸銆傞亷鍘绘椤炵敘(ch菐n)鍝佸ぇ澶氶€氶亷鍣存秱鍟炲厜婕嗕締瀵︾従(xi脿n)浣庡厜婢ゅ害锛屼絾鏄櫞婕嗗皪鐠�(hu谩n)澧冩薄鏌撹純澶э紝涓斾娇寰楁潗鏂欏洖鏀跺洶闆�锛岀洰鍓嶈秺渚嗚秺澶氱殑寤犲闁嬪閲囩敤浣庡厜婢�PC/ABS鍚堥噾锛岀渷鍘讳簡鍣存紗鐨勬椹�锛屾彁楂樹簡鐢熺敘(ch菐n)鏁堢巼鍜屽悎鏍肩巼锛岄檷浣庝簡鎴愭湰銆�
?
浜屻€�pc/abs fr2010 闃荤噧鏀规€у皪PC/ABS鍚堥噾鐔遍檷瑙h鐐虹殑褰遍熆锛�
鏍规摎(j霉)鏂滅巼k=-0.457E/R,鍙眰鍑轰笉鍚屽崌婧€熺巼涓嶅悓闅庢鐩告噳(y墨ng)鐨勬椿鍖栬兘(E)鍊�,瑕嬭〃4?寰炶〃4鐨勬暩(sh霉)鎿�(j霉)渚嗙湅,鏀规€у悗鐨勫悎閲�PC-510鐩告瘮PC-345娲诲寲鑳芥暩(sh霉)鍊间笅闄�,琛ㄦ槑绺介珨鑰冮噺鏅�,鍔犲叆闃荤噧鍔戜娇鏉愭枡鏁撮珨鐨勭啽绌�(w臎n)瀹氭€ч檷浣�,浣嗘槸闅ㄩ樆鐕冨姂鐨勫姞鍏�,鏈€澶у垎瑙f韩搴﹀崌楂�,涓斿湪楂樺姞鐔遍€熺巼涓嬭〃鐝�(xi脿n)寰楄純鐐烘槑椤�,閫欒鏄庤仛鍚堢墿瑕侀仈鍒扮浉鍚岀殑鍒嗚В绋嬪害闇€瑕佺殑鏅傞枔寤堕暦,寰炶€屽欢绶╀簡鏉愭枡鐨勫垎瑙i亷绋�?
?
涓�銆佸唬妤�(y猫)濉戣啝鍘熸枡鏈夐檺鍏徃浠ュ鎴剁偤鏍规湰锛屽爡鎸佽蛋姝e搧銆侀珮鍝佽唱(zh矛)銆佸劒(y艒u)鏈嶅嫏(w霉)璺窔銆傞姺鍞細pc/abs fr2010, PC/ABS鍚堥噾绲�(ji茅)鍚堜簡ABS鍜�PC鐨勯珮鎬ц兘鍎�(y艒u)鍕㈤€茶浜掕锛屽叡娣峰悎閲戠殑鑰愮啽鎬с€佹矕鎿婂挤搴︿互鍙婃媺浼稿挤搴﹀劒(y艒u)浜� ABS锛岃€屼笖鍏剁啍楂旂矘搴︽瘮 PC浣庯紝鍔犲伐鎬ц兘濂�锛屽埗鍝佸収(n猫i)鎳�(y墨ng)鍔涘拰娌栨搳寮峰害灏嶅埗鍝佸帤搴︾殑鏁忔劅鎬ч兘澶уぇ闄嶄綆锛屽湪闆诲瓙闆绘埃銆佹苯杌婁互鍙婅ū澶氶珮鏂版妧琛�(sh霉)闋�(l菒ng)鍩熺敤閫斿唬娉�銆傛垜鍙镐富鐕熸湁寰峰湅绉戞€濆壍(chu脿ng)PC/ABS锛屾矙浼熀绀�(ch菙)PC/ABS锛屾棩鏈笣浜�PC/ABS锛屾棩鏈笁鑿�PC/ABS锛岄煋鍦�LG鍖栧(xu茅)PC/ABS锛岄煋鍦嬩笁鏄�PC/ABS锛岃嚭鐏h嚭鍖�PC/ABS锛岃嚭鐏e缇�PC/ABS绛夈€�
?
鍥�銆乸c/abs fr2010 鐢�(ch菐n)鍝佸湒鐗囷細
浜斻€乸c/abs fr2010 PC/ABS 鍚堥噾娴佸嫊鎬ф敼鍠勭殑鐮旂┒锛�
鍙︿竴鏂归潰锛�PBT 鍏锋湁鑹ソ鐨勬祦鍕曟€�锛屽叾鍓垏璁婄█鐝�(xi脿n)璞℃槑椤�锛屽叾鍔犲叆PC /ABS 鍚堥噾楂旂郴鍚�锛屼娇寰楅珨绯绘祦鍕曟€у緱鍒板ぇ骞呯殑鎻愬崌銆傚壀鍒囪畩绋€鐝�(xi脿n)璞℃槸鍏稿瀷鐨勯珮鍒嗗瓙鐔旈珨闈炵墰闋撴祦楂旀€ц唱(zh矛)锛屽湪鍓垏鍔涚殑浣滅敤涓嬮珮鍒嗗瓙閺堟鍙栧悜鍔犲挤锛岃В绾忓姞寮凤紝琛ㄧ従(xi脿n)鐐鸿〃瑙€榛忓害鐨勪笅闄嶃€傞櫎浜嗛€氶亷娴佽畩鍎€灏嶉珮鍒嗗瓙娴佽畩鎬ц兘鐨勬脯瑭︿箣澶�锛屽闅涚敓鐢�(ch菐n)涓€氬父鍒╃敤鏉愭枡鍦ㄥ悓涓€姊濅欢涓嬫敞濉戠壒瀹氳灪鏃嬫ā鍏风殑铻烘棆娴佸嫊鎸囨暩(sh霉)閫茶灏嶆瘮銆傚湪娉ㄥ姗熺殑鐪熷鍓垏姊濅欢涓�锛岃兘澶犳ā鎿潗鏂欏湪娉ㄥ閬庣▼涓祦鍕曟€х殑璁婂寲銆傝〃5鍒楄垑浜嗘墍鐢ㄥ師鏂欏拰鍚堥噾鏉愭枡鐨勮灪鏃嬫祦鍕曟寚鏁�(sh霉)( 娉ㄥ婧害245锝�250 鈩�锛屾敞濉戝鍔�80 MPa锛屾敞濉戦€熷害鐐轰腑閫�) 銆傚緸绲�(ji茅)鏋滃彲浠ョ湅鍒�锛岀敱浜�PBT 鐨勫壀鍒囨祦鍕曟€ц兘鑹ソ锛屼娇寰楅珨绯荤殑娴佸嫊鎬у緱鍒颁簡妤典匠鐨勬敼鍠�銆�
?
鍏�銆�pc/abs fr2010 鑱氱7閰搁叝闃荤噧鍔戝皪PC/ABS鍚堥噾闃荤噧鎬ц兘褰遍熆锛�
Influence of polyphosphate flame retardant on PC/ABS alloy
GOU Jia,SHEN Huiying,CHEN Chao,QIN Wei,GONG Wei,BAN Daming
(School of Chemistry and Materials Science,Guizhou Normal University,Guiyang 550001,China)
Abstract:A novel flame retardant,poly(2-10-hydrogen-9-oxa-phosphaphenanthrene hydroquinone phenyl phosphate)(POPP),was incorporated to PC/ABS to improve the flame retardancy of PC/ABS.Flame retardant properties of PC/ABS were investigated by limited oxygen index test,vertical combustion test,thermal gravimetric analysis test,cone calorimetric test and scanning electron microscopy test.The results showed that the addition of 15% POPP to PC/ABS could achieve UL-94V-0grade with LOI value of 21.1%.The cone test showed that peak of heat release rate and total heat release decreased by 41.7%and 31.1%,respectively.TGA and SEM analysis demonstrated that the modified PC/ABS alloy exhibited better char bing effect,which promoted the bation of dense porous carbon layer on the surface after combustion,and effectively insulated the oxygen to improve the flame retardant properties of the material.
Key words:PC/ABS;modification;flame retardancy;polyphosphate
?
涓�銆�pc/abs fr2010 閲囪臣鑱�(li谩n)绯绘柟寮忥細
鑱�(li谩n)绯诲湴鍧€锛氬唬鏉辩渷鏉辫帪甯傛鏈ㄩ牠濉戣啝鍟嗗嫏(w霉)涓績
鑱�(li谩n)绯婚浕瑭�/寰俊锛�13412886878锛堥劎鐢燂級
鍌崇湡铏熺⒓锛�0769-82933089
楱拌▕ QQ锛�673160582
?
鍏�銆佸師鏂欒鎯呭垎鏋�--鏈懆涓佽嫰姗¤啝甯傚牬琛屾儏灏忓箙涓婃疾(8.5-8.9)?? pc/abs fr2010
08鏈�11鏃ヨ▕
??涓€銆佽蛋鍕㈠垎鏋�
??鎿�(j霉)鐢熸剰绀炬暩(sh霉)鎿�(j霉)鐩�(ji膩n)娓�锛屾湰鍛�(8.5-8.9)鍦嬪収(n猫i)涓佽嫰姗¤啝鍍规牸灏忓箙涓婃疾锛屽懆鍒濆児鏍煎湪10700鍏�/鍣�锛屽懆鏈児鏍煎湪10800鍏�/鍣�锛屽児鏍煎皬骞呬笂婕�0.93%銆�
??浜�銆佽鎯呭垎鏋�
??瑁濈疆鏂归潰锛氱洰鍓嶅湅鍏�(n猫i)涓佽嫰姗¤啝浼佹キ(y猫)闄哥簩(x霉)闄嶈矤锛屾禉姹熺董娉�銆佷腑鐭冲寲鎻氬瓙銆佷腑鐭虫补鍚夊寲绛変竵鑻鑶犺缃礇绱涢檷璨犻亱琛岋紝涓佽嫰姗¤啝渚涙噳(y墨ng)澹撳姏鏈夋墍绶╄В銆�
??姗¤啝閫插嚭鍙o細鍦嬪収(n猫i)鍚堟垚姗¤啝閫插彛閲忔暣楂旀笡灏�锛屽皪涓佽嫰姗¤啝鍍规牸褰㈡垚鏀拹銆傛摎(j霉)娴烽棞(gu膩n)绲�(t菕ng)瑷�,2019骞�7鏈堜唤鎴戝湅澶╃劧鍙婂悎鎴愭鑶犻€插彛閲忕偤55.3钀櫢,1-7鏈堢偤362.9鍣�銆傝垏鍘诲勾鍚屾湡鐩告瘮娓涘皯7.1%銆�
??鍘熸枡鏂归潰锛氬師鏂欎竵浜岀儻鏈懆鍍规牸澶у箙涓婃疾锛屾垚鏈潰灏嶄竵鑻鑶犲舰鎴愭敮鎾�銆傛摎(j霉)鐢熸剰绀剧洠(ji膩n)娓湰鍛ㄤ竵浜岀儻鍛ㄥ垵9534鍏�/鍣�锛屽懆鏈�9934鍏�/鍣�锛屾暣楂斾笂婕�4.20%銆�
??闇€姹傛柟闈細鎿�(j霉)绲�(t菕ng)瑷堬紝2019骞�6鏈堝湅鍏�(n猫i)姗¤啝杓儙澶栬儙鐢�(ch菐n)閲忕偤7027.9钀锛岀挵(hu谩n)姣斾笅婊�2.45%锛屽悓姣斾笂婕�3.2%锛�1-6鏈堝湅鍏�(n猫i)姗¤啝杓儙澶栬儙鐢�(ch菐n)閲忕偤40374.5钀锛屽悓姣斾笅婊�1.0%銆�
?涓夈€佸悗甯傚睍鏈�
??鐢熸剰绀惧垎鏋愬斧寰愭泬鏄嗚獚鐐�锛岀洰鍓嶄締鐪嬩竴鏂归潰涓婃父涓佷簩鐑児鏍奸珮浣�锛屽皪鍚堟垚鑶犲児鏍煎舰鎴愭敮鎾�锛屽彟涓€鏂归潰涓佽嫰閮ㄥ垎寤犲闄嶈矤閬嬭锛岄爯(y霉)鏈熷悗鏈熷競鍫磋波婧愬亸绶�銆傜稖鍚堜締鐪嬪悗鏈熶締鐪嬩竵鑻鑶犲競鍫存垨?q奴)鈷梌绾�(x霉)瑭︽帰鎬т笂婕层€�