PPS浣滅偤楂樻€у児(ji脿)姣旂殑鐗圭ó宸ョ▼濉戞枡锛屽叾缍滃悎鎬ц兘鍎�(y艒u)鑹�銆佸垎瀛愮祼(ji茅)妲�(g貌u)鐛�(d煤)鐗�锛屽凡鍦�鑸┖鑸ぉ銆佸湅(gu贸)闃茶粛宸ャ€佹牳宸ユキ(y猫)銆佹(j墨)姊板剙琛ㄣ€侀浕瀛愰浕姘�銆侀鍝佽垏钘ュ搧宸ユキ(y猫)浠ュ強楂樻柊鎶€琛�(sh霉)闋�(l菒ng)鍩�浣滅偤鑰愰珮婧�銆佽€愰樆鐕�銆侀珮鎬ц兘鐨勯潪閲戝爆鏉愭枡鐛插緱寤ｆ硾鎳�(y墨ng)鐢�銆�

1888骞碢(gu膩n)PS妯�(sh霉)鑴備綔鐐哄弽鎳�(y墨ng)鐨勫壇鐢�(ch菐n)鐗╄浜哄€戠櫦(f膩)鐝�(xi脿n)銆�1968骞寸敱缇庡湅(gu贸)Philips鐭虫补鍏徃闁�(k膩i)鐧�(f膩)锛�1973骞村(sh铆)鐝�(xi脿n)宸ユキ(y猫)鍖栥€侾PS鐨勮粺鍖栭粸(di菐n)鐐�277~282鈩�锛岀幓鐠冨寲杞�(zhu菐n)璁婃韩搴�(Tg)鐐�85~93鈩冦€傜洰鍓�锛岀編鍦�(gu贸)銆佹棩鏈拰姝愭床灏�(du矛)浜嶱PS鐨勭爺绌堕枊(k膩i)鐧�(f膩)铏曚簬鍦颁綅銆�

2016骞村叏鐞働PS闇€姹傞噺绱勭偤10钀�(w脿n)t锛岄€欐鍔熶簬姹借粖琛屾キ(y猫)濡傚偝鎰熷櫒鐨勬噳(y墨ng)鐢ㄦ暩(sh霉)閲忕殑澧炲姞銆傚氨鍏ㄧ悆鑼冨湇鑰岃█锛屾棩鏈槸PPS鐢熺敘(ch菐n)澶у湅(gu贸)锛岀敘(ch菐n)鑳藉崰鍏ㄤ笘鐣岀殑50%浠ヤ笂銆�

鎴戝湅(gu贸)灏嘝PS鐮旂┒鍒楀叆“863”瑷�(j矛)鍔冿紝鐢卞洓宸濆ぇ瀛�(xu茅)鎵挎摂(d膩n)瑭茬爺绌�銆�1986骞村洓宸濆ぇ瀛�(xu茅)鎴愬姛闁�(k膩i)鐧�(f膩)PPS鐢熺敘(ch菐n)宸ヨ棟锛屽湪鍥涘窛鐪佽嚜璨㈠競鍖栧(xu茅)瑭﹀姂寤犲缓鎴�9t/a鐨勭敓鐢�(ch菐n)瑁濈疆锛屽搧璩�(zh矛)閬�(d谩)鍒板湅(gu贸)闅涙(bi膩o)婧�(zh菙n)銆傜洰鍓�锛屾垜鍦�(gu贸)PPS妯�(sh霉)鑴傚強鏀规€у京(f霉)鍚堟潗鏂欓渶姹傚法澶э紝鐢�(ch菐n)閲忕磩鐐�4钀�(w脿n)t/a銆�

涓€.PPS鐨勭祼(ji茅)妲�(g貌u)鑸囨€ц兘

PPS鎬ц兘鍎�(y艒u)鑹紝灏ゅ叾閫氶亷(gu貌)澧炲挤(qi谩ng)銆佹敼鎬с€佸叡娣峰悎閲戝寲鍙婂師浣嶅京(f霉)鍚堟妧琛�(sh霉)鍒舵垚浜嗙敤閫斿唬娉涚殑鍚勭ó寰�(f霉)鍚堟潗鏂�銆�

PPS鏈夊崄鍒嗗劒(y艒u)鐣扮殑鐔辨€ц兘銆侀浕鎬ц兘銆佽€愬寲瀛�(xu茅)鎬ц兘銆佽€愯蓟灏�銆侀樆鐕冪瓑鎬ц兘锛屽绱擯PS鐨勬サ闄愭哀鎸囨暩(sh霉)鍙珮閬�(d谩)44%锛岄噰鐢ㄧ幓鐠冪簴缍�(GF)/绀︾墿濉厖PPS姘ф寚鏁�(sh霉)鍙珮閬�(d谩)53%銆侾PS鐨勫垎瀛愮祼(ji茅)妲�(g貌u)姹哄畾浜嗗叾鎬ц兘锛岃肠浜堜簡鍏剁崹(d煤)鐗圭殑鐗╃悊鍖栧(xu茅)鐗规€�(瑕�(ji脿n)鍦�1)銆�

鐐轰簡閫�(j矛n)涓€姝ユ敼鍠凱PS鐨勬€ц兘锛屾摯(ku貌)澶ч仼鐢ㄨ寖鍦�锛岄爤灏�(du矛)鍏堕€�(j矛n)琛屾敼鎬х爺绌�锛屼互閬�(d谩)鍒颁互涓�5鍊�(g猫)鐩殑:

鐮旂┒琛ㄦ槑锛孭PS娣诲姞鐒�(w煤)姗�(j墨)濉枡鍚庝粛鑳借垏鍏朵粬鑱氬悎鐗╂湁鑹ソ鐨勭浉瀹规€�锛岄€欑偤鍏跺悎閲戝寲鍜屽京(f霉)鍚堟敼鎬у壍(chu脿ng)閫犱簡鏈夊埄姊濅欢銆傛渶鏃╅枊(k膩i)鐧�(f膩)鎴愬姛鐨勬槸PPS鑸囨盁濉戞枡鍏辨贩鍚堥噾锛屾鍚庡舰鎴愪簡鍚堥噾绯诲垪銆�

PPS鍚堥噾鍖栧悗鎷変几寮�(qi谩ng)搴�銆佸綆鏇插挤(qi谩ng)搴︺€佹姉娌栨搳鎬ц兘銆佽€愮啽鎬ц兘澶у箙鎻愰珮锛岀偤閫�(j矛n)涓€姝ョ殑鎿犲嚭銆佸惞濉戞垚鍨嬪伐钘濈殑瀵�(sh铆)鏂芥彁渚涗簡鍙兘銆�

鐩墠锛屽叏涓栫晫閵峰敭鐨凱PS寰�(f霉)鍚堟敼鎬у搧绋閬�(d谩)200浣欑ó锛屼富瑕佹湁GF澧炲挤(qi谩ng)銆佺⒊绾栫董(CF)澧炲挤(qi谩ng)銆佺劇(w煤)姗�(j墨)濉枡濉厖銆丟F鍜屽～鏂欏叡鍚屽～鍏呭寮�(qi谩ng)绛夊叡娣锋敼鎬�銆�

绛嗚€呴伕鍙�8闋�(xi脿ng)PPS鍏辨贩寰�(f霉)鍚堟敼鎬ч厤鏂瑰(sh铆)渚嬪拰鏀规€х爺绌堕€�(j矛n)灞�锛屼互渚涘弮鑰�:

(1) 鎶楅潨闆籔PS寰�(f霉)鍚堟潗鏂欓厤鏂�銆�

PPS绮�50%(璩�(zh矛)閲忓垎?j菒n)?sh霉)锛屼笅鍚�)锛屽ぉ鐒堕睏鐗囩媭鐭冲ⅷ5%锛屽皫(d菐o)闆绘€х煶澧�2%锛岀～閰搁垼浜屾按鍚堢墿寰矇22%锛孏F21%銆傛脯(c猫)瑭︾祼(ji茅)鏋滆〃鏄�:瑭查厤鏂规姉闈滈浕鎬�銆佹垚鍨嬪姞宸ユ祦鍕�(d貌ng)鎬�銆佸姏瀛�(xu茅)鎬ц兘鍙婂昂瀵哥┅(w臎n)瀹氭€у潎鍎�(y艒u)鑹紝鍙噳(y墨ng)鐢ㄤ簬閷勫儚姗�(j墨)銆侀浕瑕栧拰闆昏叇鐨勭鐗囧強鍏夐﹨(q奴)锛屼互鍙婅姹傛湁鎶楅潨闆荤殑鍏夐浕鍣ㄦ潗鎴栭浕纾佸櫒鏉�銆�

(2)绾栫董濉厖PPS鍚堥噾閰嶆柟銆�

PPS18%~54%锛岃仛鑻啔(PPE)6%~42%锛岀劇(w煤)姗�(j墨)绾栫董40%锛岀浉瀹瑰姂閬╅噺銆傛脯(c猫)瑭︾祼(ji茅)鏋滆〃鏄�:瑭查厤鏂硅€愮啽鎬с€佸昂瀵哥┅(w臎n)瀹氭€уソ锛屽彲鎳�(y墨ng)鐢ㄤ簬姹借粖姘ｇ几钃�銆�
(3)鐒�(w煤)姗�(j墨)鐗╁～鍏匬PS閰嶆柟銆�

PPS29%~91%锛岀櫧浜戠煶(骞冲潎绮掑緫2锛�5μm)9%~71%銆傛脯(c猫)瑭︾祼(ji茅)鏋滆〃鏄�:瑭查厤鏂规湁鍎�(y艒u)鑹殑鍓涙€�銆佸昂瀵哥┅(w臎n)瀹氭€у強闃荤噧鎬э紝骞舵湁妤靛ソ鐨勮〃闈㈠厜婊戞€�銆侀珮寮�(qi谩ng)搴︺€佺啽绌�(w臎n)瀹氭€�锛屽彲鎳�(y墨ng)鐢ㄤ簬闆诲櫒銆佹(j墨)姊扮殑鎻掓帴浠�銆�

(4)PPS鐨勬饯(r霉n)婊戝強鑰愮（閰嶆柟銆�

鑱氬洓姘熶箼鐑�(PTFE)20%~60%锛孭PS40%~80%銆傛脯(c猫)瑭︾祼(ji茅)鏋滆〃鏄�:瑭查厤鏂瑰吋鏈塒PS鐨勬垚鍨嬪姞宸ユ€у拰鍔涘(xu茅)寮�(qi谩ng)搴︼紝骞朵笖鍏锋湁PTFE妤靛ソ鐨勬饯(r霉n)婊戞€�锛屽彲鎳�(y墨ng)鐢ㄤ簬鎶楃（鍙婅€愮（鏉愭枡銆�

(5)PPS鑸囧伐绋嬪鏂欏悎閲戦厤鏂广€�

PPS40%~90%锛岃仛閰颁簽鑳�(PI)5%~55%锛孭PE5%~55%锛岀浉瀹瑰姂閬╅噺銆傛脯(c猫)瑭︾祼(ji茅)鏋滆〃鏄�:瑭查厤鏂瑰埗寰楃殑鐢�(ch菐n)鍝佹槗浜庝笂婕�锛屽叿鏈夎純楂樼殑娌栨搳鎬ц兘鍜屽昂瀵哥┅(w臎n)瀹氭€э紝鍙噳(y墨ng)鐢ㄤ簬姹借粖澶栬椋炬潗鏂�銆�

绶氭€PS40%锛岀窔鎬т笉椋藉拰鍖栧悎鐗�(甯舵湁鐑村熀銆佺景鍩�銆侀吀閰愭垨鐠�(hu谩n)姘у畼鑳藉湗(tu谩n)鐨勭窔鎬т笉椋藉拰鍖栧悎鐗�)40%锛岀彔鍏変簯姣嶇矇8%锛屾湁姗�(j墨)鎴栫劇(w煤)姗�(j墨)绾栫董12%銆�

娓�(c猫)瑭︾祼(ji茅)鏋滆〃鏄�:瑭查厤鏂圭殑鑰愮啽鎬у拰鍓涙€у劒(y艒u)鐣�锛屽悓鏅�(sh铆)鍏锋湁鑹ソ鐨勫姞宸ユ€ц兘銆佽€愭矕鎿婂拰娼�(r霉n)婊戞€�锛屽彲鎳�(y墨ng)鐢ㄤ簬闆诲櫒銆侀浕瀛愬拰绮惧瘑鍎€鍣ㄧ殑閼勫皝鏉愭枡銆�

(7)姘у寲閶呮櫠闋�(ZnOw)澧炲挤(qi谩ng)PPS灏堢敤鏂�銆�

PPS100浠�(璩�(zh矛)閲忎唤鏁�(sh霉)锛屼笅鍚�)锛孼nOw35浠斤紝鍋惰伅(li谩n)鍔�0.1~1.0浠�锛屽叾浠栧姪鍔戦仼閲�銆�

閫氶亷(gu貌)ZnOw鏀规€PS骞惰紨浠F锛屽彲鍒跺緱鎷変几寮�(qi谩ng)搴﹂珮銆佹姉闈滈浕鎬ц兘濂界殑寰�(f霉)鍚堟潗鏂欍€傜暥(d膩ng)ZnOw娣诲姞璩�(zh矛)閲忎唤鏁�(sh霉)鐐�30浠�锛孏F娣诲姞璩�(zh矛)閲忎唤鏁�(sh霉)鐐�30浠芥檪(sh铆)锛屾媺浼稿挤(qi谩ng)搴﹂仈(d谩)128锛�5MPa锛岃〃闈㈤浕闃荤巼閬�(d谩)4锛�3×109Ω銆�

娓�(c猫)瑭︾祼(ji茅)鏋滆〃鏄�:PPS/ZnOw鎶楅潨闆诲京(f霉)鍚堟潗鏂欏叿鏈夊劒(y艒u)鑹殑鍚告尝鎬ц兘锛屽彲鎳�(y墨ng)鐢ㄤ簬寰尝鐧�(f膩)鐔辨潗鏂欏拰闆绘尝鍚告敹鏉愭枡锛屽湪璜稿闋�(l菒ng)鍩熷叿鏈夊唬娉涚殑鎳�(y墨ng)鐢ㄥ墠鏅€�

(8)绱嶇背浜屾哀鍖栫(Nano-SiO2)鏀规€PS灏堢敤鏂欍€�
PPS100浠�锛孨ano-SiO23锛�0浠斤紝鍋惰伅(li谩n)鍔�0锛�1~1锛�0浠�锛屽叾浠栧姪鍔戦仼閲�銆傛脯(c猫)瑭︾祼(ji茅)鏋滆〃鏄�:鏀规€ф潗鏂欑殑鎷変几寮�(qi谩ng)搴﹀拰鎷変几妯￠噺鍒嗗垾鎻愰珮13锛�4%鍜�6锛�0%锛屽綆鏇插挤(qi谩ng)搴﹀拰褰庢洸妯￠噺鍒嗗垾鎻愰珮6锛�5%鍜�7锛�4%銆�

鐢辨琛ㄦ槑锛孨ano-SiO2鑳介’钁楁彁楂楶PS鐨勫姏瀛�(xu茅)鎬ц兘鍜岀稖鍚堟€ц兘锛屽厖鍒嗛’绀哄嚭鐒�(w煤)姗�(j墨)绱嶇背绮掑瓙鍦ㄥ鏂欐敼鎬т腑鐨勫劒(y艒u)鐣扮壒鎬с€�

鑰冨療浜嗙磵绫崇⒊閰搁垼(Nano-CaCO3)鐢ㄩ噺鍙婅〃闈㈣檿鐞嗗姂灏�(du矛)鐜荤拑绾栫董澧炲挤(qi谩ng)鑱氳嫰纭啔(PPS/GF)寰�(f霉)鍚堟潗鏂欏姏瀛�(xu茅)鎬ц兘鐨勫奖闊�銆�
绲�(ji茅)鏋滆〃鏄�:闅ㄨ憲Nano-CaCO3璩�(zh矛)閲忓垎?j菒n)?sh霉)鐨勫鍔狅紝瑭︽ǎ鐨勬矕鎿婂挤(qi谩ng)搴﹀拰褰庢洸寮�(qi谩ng)搴﹀潎鏈変笉鍚岀▼搴︾殑鎻愰珮;骞朵笖缍�(j墨ng)閳﹂吀閰伓鑱�(li谩n)鍔戣檿鐞嗙殑Nano-CaCO3姣旂敤纭剛閰歌檿鐞嗙殑鏁堟灉鏇村ソ銆�
閲囩敤姘у寲閹傚皪(du矛)PPS閫�(j矛n)琛屽皫(d菐o)鐔辨敼鎬х爺绌�锛屽皪(du矛)姣斾簡涓嶅悓绮掑緫姘у寲閹傚柈鐛�(d煤)浣跨敤銆佷笉鍚岀矑寰戞哀鍖栭巶寰�(f霉)閰嶄娇鐢�銆佸凹榫�66(PA66)妯�(sh霉)鑴備互鍙婃瘝绮掓硶灏�(du矛)PPS寰�(f霉)鍚堟潗鏂欏皫(d菐o)鐔辩巼鐨勫奖闊�锛岀爺绌朵簡GF鍜孋F灏�(du矛)灏�(d菐o)鐔盤PS寰�(f霉)鍚堟潗鏂欑殑澧炲挤(qi谩ng)鏀规€с€�

绲�(ji茅)鏋滆〃鏄�:姘у寲閹傚彲浠ユ湁鏁堟敼鍠凱PS鐨勫皫(d菐o)鐔辩巼锛屼笉鍚岀矑寰戞哀鍖栭巶鐨勫京(f霉)閰嶄娇鐢ㄣ€丳A66妯�(sh霉)鑴傚拰姣嶇矑娉曠殑鍚堢悊浣跨敤鍙互閫�(j矛n)涓€姝ユ彁楂楶PS鐨勫皫(d菐o)鐔辩巼锛孏F鍜孋F鍙互灏�(du矛)灏�(d菐o)鐔盤PS寰�(f霉)鍚堟潗鏂欒捣鍒版槑椤殑澧炲挤(qi谩ng)浣滅敤銆�

MASAMOTOJ绛夐噰鐢ㄤ簩鑻熀鐢茬兎浜岀暟姘伴吀閰�(MDI)閫氶亷(gu貌)鐔旇瀺鍙嶆噳(y墨ng)鎿犲嚭鐨勮睛娉曞皪(du矛)PPS鍏堥€�(j矛n)琛屽寲瀛�(xu茅)鏀规€э紝寮曞叆—NCO鍩哄湗(tu谩n)鍐嶈垏浣滅偤澧為煂褰堟€ч珨鐨勪箼鐑熀涓欑儻閰搁叝鎺ユ灊棣締(l谩i)閰搁厫鐔旇瀺鍏辨贩寰楀埌澧為煂PPS銆�

绲�(ji茅)鏋滆〃鏄�:褰堟€ч珨鑸嘝PS鍩洪珨鍏锋湁鑹ソ鐨勭浉瀹规€�锛孧DI鏀规€х殑PPS鑸囧付鍙嶆噳(y墨ng)鎬у熀鍦�(tu谩n)鐨勫綀鎬ч珨閬�(d谩)鍒颁簡鍙嶆噳(y墨ng)鎬у瀹圭殑鐩殑;褰堟€ч珨绮掑緫瓒婂皬锛岀己鍙ｆ矕鎿婂挤(qi谩ng)搴﹁秺楂�锛屽苟涓斿瓨鍦�“鑴�-闊�”杞�(zhu菐n)璁婄殑鑷ㄧ晫鐩村緫鍜岃嚚鐣屽綀鎬ч珨椤嗙矑闁撹窛銆�
閲囩敤CF鍜岀⒊绱嶇背绠�(CNTs)澧炲挤(qi谩ng)PPS鐨勫姏瀛�(xu茅)鎬ц兘鍜屽皫(d菐o)闆绘€�銆傜祼(ji茅)鏋滆〃鏄�:鍠祫鍒嗘敼鎬PS锛孋F鍜孋NTs鐨勮唱(zh矛)閲忓垎?j菒n)?sh霉)鍒嗗垾鐐�20%銆�15%鏅�(sh铆)锛屽京(f霉)鍚堟潗鏂欑殑鍔涘(xu茅)鎬ц兘鍜屽皫(d菐o)闆绘€ц兘杓冪悊鎯�;閲囩敤CF鍜孋NTs寰�(f霉)鍚堝寮�(qi谩ng)PPS锛岀暥(d膩ng)CF鐨勮唱(zh矛)閲忓垎?j菒n)?sh霉)鐐�16%銆丆NTs鐨勮唱(zh矛)閲忓垎?j菒n)?sh霉)鐐�4%鏅�(sh铆)锛孋NTs/CF/PPS寰�(f霉)鍚堟潗鏂欐€ц兘杓冨ソ銆�

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绲�(ji茅)鏋滆〃鏄�:鍔犲叆閬╅噺鐨凱C妯�(sh霉)鑴傦紝鍙湪涓€瀹氱▼搴︿笂鎻愰珮PPS妯�(sh霉)鑴傜殑灞堟湇寮�(qi谩ng)搴�銆佹媺浼告柗瑁傚挤(qi谩ng)搴�銆佸綆鏇插挤(qi谩ng)搴﹀強娌栨搳闊屾€с€�
鐐烘彁楂楶PS鐨勮€愮（鎬ц兘锛岄噰鐢ㄤ簡璩�(zh矛)閲忓垎?j菒n)?sh霉)鍧囩偤40%鐨凣F鍜孋F澧炲挤(qi谩ng)PPS锛岀爺绌跺皪(du矛)姣斾簡瀹冨€戠殑鎽╂摝纾ㄦ悕鎬ц兘锛岀櫦(f膩)鐝�(xi脿n)CF澧炲挤(qi谩ng)PPS鐨勬懇鎿︾郴鏁�(sh霉)鍜岀（鎼嶇巼鍧囦綆浜嶨F澧炲挤(qi谩ng)PPS銆�
鍦ㄦ鍩虹(ch菙)涓�锛岄噰鐢≒TFE鍜孨ano-SiO2灏�(du矛)GF澧炲挤(qi谩ng)PPS閫�(j矛n)琛屽京(f霉)鍚堣€愮（鏀规€�锛岀爺绌朵簡PTFE鍜孨ano-SiO2鍚噺灏�(du矛)GF澧炲挤(qi谩ng)PPS鎽╂摝纾ㄦ悕鎬ц兘鍙婇浕绲曠罚鎬ц兘鐨勫奖闊�銆�

绲�(ji茅)鏋滆〃鏄�:鐩稿皪(du矛)浜庤唱(zh矛)閲忓垎?j菒n)?sh霉)鐐�40%鐨凜F澧炲挤(qi谩ng)PPS锛屽湪鐩稿悓璩�(zh矛)閲忓垎?j菒n)?sh霉)鐨凣F澧炲挤(qi谩ng)PPS涓噰鐢ㄨ唱(zh矛)閲忓垎?j菒n)?sh霉)鍧囩偤10%鐨凱TFE鍜孨ano-SiO2锛屽彲浠ュ湪杓冧綆鎴愭湰涓嬩娇鍏剁嵅寰楁洿浣庣殑鎽╂摝绯绘暩(sh霉)銆佺（鎼嶇巼锛屼互鍙婃痪鍕�(d貌ng)鎽╂摝?x铆)r鐨勭（鎼嶈唱(zh矛)閲忓拰纾ㄦ悕楂旂⿳锛屽悓鏅�(sh铆)淇濇寔鑹ソ鐨勯浕绲曠罚鎬ц兘銆�

閲囩敤绋€鍦熻〃闈㈡敼鎬у姂灏�(du矛)Nano-CaCO3閫�(j矛n)琛岃〃闈㈡敼鎬у苟琛ㄥ緛锛岃€冨療浜嗙█鍦熺磵绫虫瘝绮掑惈閲忓皪(du矛)PPS鍔犲伐鎬ц兘鍜屽姏瀛�(xu茅)鎬ц兘鐨勫奖闊�;鐮旂┒浜哖PS/绱嶇背姣嶇矑/GF寰�(f霉)鍚堟潗鏂欑殑鍔涘(xu茅)鎬ц兘銆侀浕鎬ц兘鍙婂井瑙€绲�(ji茅)妲�(g貌u)銆�

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